Tris(μ2-methanolato)-μ3-oxido-tris{[(E)-4-chloro-2-({[2-(pyridin-2-yl)ethyl]imino}methyl)phenolato]manganese(III)} perchlorate–dichloromethane–diethyl ether (1/1.1/0.9)
نویسندگان
چکیده
In the title compound, [Mn3(C14H12ClN2O)3(CH3O)3O]ClO4·1.1CH2Cl2·0.9C4H10O, the cation consists of a central Mn3O core with μ2-methano-late bridging between adjacent MnIII atoms, thus giving each MnIII atom a mer-O3 coordination environment. Six-coordination for each MnIII atom is provided by the deprotonated Schiff base ligand (E)-4-chloro-2-({[2-(pyridin-2-yl)eth-yl]imino}-meth-yl)phenolate. There are extensive C-H⋯O and C-H⋯Cl inter-actions, which link the cations, anions, and solvent mol-ecules into a three-dimensional array.
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عنوان ژورنال:
دوره 73 شماره
صفحات -
تاریخ انتشار 2017